Binuclear Complex

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Binuclear complex is a class of complexes containing two metal centers in its chemical structure. These metal centers are connected by bridging ligands (commonly) or metal-metal interactions. The metal centers could be the same or different. There are four types of these complexes including: 1) Homo Metal Symmetric Binuclear Complexes, 2) Homo Metal Asymmetric Binuclear Complexes[1], 3) Hetero Metal Symmetric Binuclear Complexes, 4) Hetero Metal Asymmetric Binuclear Complexes. For example binuclear complexes of cadmium[2], lead[3], copper[4], mercury[5][6] and zinc[7] have been reported.

References

  1. Hakimi, Mohammad, Mardani, Zahra, Moeini, Keyvan, Minoura, Mao and Raissi, Heidar. "Synthesis, Characterization and Crystal Structure of a Binuclear Cadmium Iodide Complex with a Multi-N-donor Oxazolidine Ligand" Zeitschrift für Naturforschung B, vol. 66, no. 11, 2011, pp. 1122-1126. https://doi.org/10.1515/znb-2011-1106
  2. Hakimi, Mohammad, Mardani, Zahra, Moeini, Keyvan, Minoura, Mao and Raissi, Heidar. "Synthesis, Characterization and Crystal Structure of a Binuclear Cadmium Iodide Complex with a Multi-N-donor Oxazolidine Ligand Zeitschrift für Naturforschung B, vol. 66, no. 11, 2011, pp. 1122-1126. https://doi.org/10.1515/znb-2011-1106
  3. Farzin Marandi, Keyvan Moeini, Bahman Mostafazadeh, Harald Krautscheid, Structural, spectral and theoretical aspects in the coordination of a triazine-based ligand toward lead(II) with a holodirected environment, Polyhedron, Volume 133, 2017, Pages 146-154, https://doi.org/10.1016/j.poly
  4. Saghatforoush L, Moeini K, Hosseini-Yazdi SA, Mardani Z, Hajabbas-Farshchi A, Jameson HT, Telfer SG and Woollins JD. RSC Advances 2018; 8: 35625-39, https://doi.org/10.1039/C8RA07463A
  5. Farzin Marandi, Keyvan Moeini, Zahra Mardani, Harald Krautscheid. (2019) Spectral, structural and theoretical study of novel helical and linear structures of PbI2 and PbBr2 complexes with a triazine ligand. Journal of Coordination Chemistry 72:11, pages 1876-1889, https://doi.org/10.1080/00958972.2018.1426852
  6. Saghatforoush L, Moeini K, Golsanamlou V, Amani V, Bakhtiari A and Mardani Z. Inorganica Chimica Acta 2018; 483: 392-401, https://doi.org/10.1016/j.ica.2018.08.023
  7. Marandi F, Moeini K, Alizadeh F, Mardani Z, Quah CK, Loh W-S and Woollins JD. Inorganica Chimica Acta 2018; 482: 717-25, https://doi.org/10.1016/j.ica.2018.07.014

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